COMPETING PATHWAYS IN THE PHOTOLYTIC CYCLOADDITION REACTIONS OF N-ETHOXYCARBONYLAZEPINE TO [60]FULLERENE - FORMATION OF [2+4] AND [2+6] PHOTOADDUCTS

被引：15

作者：

BANKS, MR

CADOGAN, JIG

GOSNEY, I

HODGSON, PKG

LANGRIDGESMITH, PRR

MILLAR, JRA

PARKINSON, JA

SADLER, IH

TAYLOR, AT

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

[2] BP INT LTD,CTR RES & ENGN,SUNBURY TW16 7LN,MIDDX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 11期

关键词：

D O I：

10.1039/c39950001171

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photochemical reaction between [60]fullerene and N-ethoxycarbonylazepine, formed in situ by light-induced decomposition of ethyl azidoformate in benzene, produces two photoadducts in the ratio of 4:1 by formal [2 + 4] and [2 + 6] cycloaddition reactions as established by a series of high-field (600 MHz) NMR experiments.

引用

收藏

页码：1171 / 1172

页数：2

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