INFLUENCE OF COHESIVE FORCES ON GLASS TRANSITION TEMPERATURES OF POLYMERS

被引：45

作者：

LEE, WA

SEWELL, JH

机构：

[1] Ministry of Technology, Materials Department, Farnborough, Hampshire

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1968年 / 12卷 / 06期

关键词：

D O I：

10.1002/app.1968.070120612

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The relationship between cohesive energy (c.e.) or cohesive energy density (c.e.d.) and the glass transition tenperature (Tg) of polymers has been re‐examined on the basis of literature data. For polymers with Tg above 25°C., there is no correlation between published or calculated values of c.e. or c.e.d. and Tg. However, for the rest of the polymers there is a linear relationship between c.e.d. and Tg, and a broad relationship between c.e. and Tg. These results imply that c.e.d. is the regulating, though not the only, factor in determining Tg's up to values of approximately 25°C. Copyright © 1968 John Wiley & Sons, Inc.

引用

页码：1397 / &

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