HYDROFORMYLATION OF SOME FUNCTIONALIZED OLEFINS CATALYZED BY RHODIUM(I) COMPLEXES WITH PYDIPHOS AND ITS P-OXIDE

被引：66

作者：

BASOLI, C

BOTTEGHI, C

CABRAS, MA

CHELUCCI, G

MARCHETTI, M

机构：

[1] CNR,IST APPLICAZ TECN CHIM AVANZATE PROBLEMI AGRO,I-07100 SASSARI,ITALY

[2] UNIV VENICE,DIPARTIMENTO CHIM,I-30123 VENICE,ITALY

[3] UNIV SASSARI,DIPARTIMENTO CHIM,I-07100 SASSARI,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 488卷 / 1-2期

关键词：

HYDROFORMYLATION; PYRIDYLPHOSPHINES; CATALYSIS; RHODIUM; N-P LIGANDS;

D O I：

10.1016/0022-328X(94)00037-D

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chiral optically active pyridylphosphines pydiphos (10) and its P-oxide (11) were tested as ligands in rhodium(I) complexes to form catalysts for the enantioselective hydroformylation of some functionalized olefins. These hydroformylation reactions provide in most cases good chemo- and regioselectivity, but unsatisfactory enantioselectivity. In the hydroformylation of styrene, vinyl acetate and phenyl vinyl ether, the Rh-(I) complex containing the P-oxide 11 is remarkably more active than the catalyst formed with the pyridylphosphine analogue 10.

引用

页码：C20 / C22

页数：3

共 18 条

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