ENANTIOSELECTIVE PALLADIUM-CATALYZED ALLYLIC SUBSTITUTION WITH SULFUR-CONTAINING OXAZOLINE LIGANDS

被引：65

作者：

FROST, CG ^{[1
]}

WILLIAMS, JMJ ^{[1
]}

机构：

[1] LOUGHBOROUGH UNIV TECHNOL,DEPT CHEM,LOUGHBOROUGH LE11 3TU,LEICS,ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 08期

关键词：

D O I：

10.1016/S0957-4166(00)80417-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Enantiomerically pure sulfur/nitrogen ligands have been prepared in one step from amino alcohols and 2-(methylthio)benzonitrile. We have successfully employed these ligands for enantioselective palladium catalysed allylic substitution, with asymmetric induction of up to 80% ee.

引用

页码：1785 / 1788

页数：4

共 24 条

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