3',4-DI-O-METHYLCEDRUSIN - SYNTHESIS, RESOLUTION AND ABSOLUTE-CONFIGURATION

被引:70
作者
LEMIERE, G
GAO, M
DEGROOT, A
DOMMISSE, R
LEPOIVRE, J
PIETERS, L
BUSS, V
机构
[1] UNIV ANTWERP,UIA,DEPT PHARMACEUT SCI,B-2610 ANTWERP,BELGIUM
[2] GERHARD MERCATOR UNIV GESAMTHSCH DUISBURG,D-47048 DUISBURG,GERMANY
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 13期
关键词
D O I
10.1039/p19950001775
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The title compound has been synthesised in racemic form by a biomimetic reaction sequence. The two enantiomers were resolved by column chromatography of one of the synthetic intermediates. On the basis of CD results a tentative absolute configuration for the synthetic enantiomers and natural 3',4-di-O-methylcedrusin is proposed.
引用
收藏
页码:1775 / 1779
页数:5
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