3',4-DI-O-METHYLCEDRUSIN - SYNTHESIS, RESOLUTION AND ABSOLUTE-CONFIGURATION

被引：70

作者：

LEMIERE, G

GAO, M

DEGROOT, A

DOMMISSE, R

LEPOIVRE, J

PIETERS, L

BUSS, V

机构：

[1] UNIV ANTWERP,UIA,DEPT PHARMACEUT SCI,B-2610 ANTWERP,BELGIUM

[2] GERHARD MERCATOR UNIV GESAMTHSCH DUISBURG,D-47048 DUISBURG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 13期

关键词：

D O I：

10.1039/p19950001775

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound has been synthesised in racemic form by a biomimetic reaction sequence. The two enantiomers were resolved by column chromatography of one of the synthetic intermediates. On the basis of CD results a tentative absolute configuration for the synthetic enantiomers and natural 3',4-di-O-methylcedrusin is proposed.

引用

页码：1775 / 1779

页数：5

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