BENZOTRIAZOLATE-MEDIATED ASSEMBLY OF THE DISCRETE ASYMMETRIC PENTANUCLEAR NICKEL-COMPLEX [NI-5(OH)(BTA)(5)(ACAC)(4)(H2O)(4)] (HBTA=BENZOTRIAZOLE, HACAC=PENTANE-2,4-DIONE)

被引：38

作者：

BAKALBASSIS, EG

DIAMANTOPOULOU, E

PERLEPES, SP

RAPTOPOULOU, CP

TANGOULIS, V

TERZIS, A

ZAFIROPOULOS, TF

机构：

[1] UNIV PATRAS,DEPT CHEM,GR-26500 PATRAI,GREECE

[2] NRCPS DEMOKRITOS,INST MAT SCI,GR-15310 ATHENS,GREECE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 13期

关键词：

D O I：

10.1039/c39950001347

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [Ni(acac)(2)(H2O)(2)] with benzotriazole (Hbta) in acetone-n-hexane yields the pentanuclear nickel complex: [N i(5)(OH)(bta)(5)(acac)(4)(H2O)4] 1; the novel structure of this compound is described, together with the results of magnetic susceptibility studies which indicate antiferromagnetic coupling between the nickel (II) ions within the complex.

引用

页码：1347 / 1348

页数：2

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