PALLADIUM(0)-CATALYZED ALLYLATION OF 4(5)-SUBSTITUTED IMIDAZOLES, 5(6)-SUBSTITUTED BENZIMIDAZOLES, BENZOTRIAZOLE AND 5(6)-METHYLBENZOTRIAZOLE

被引：20

作者：

ARNAU, N

ARREDONDO, Y

MORENOMANAS, M

PLEIXATS, R

VILLARROYA, M

机构：

[1] Department of Chemistry, Universitat Autònoma de Barcelona, Barcelona, 08193, Bellaterra

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 1995年 / 32卷 / 04期

关键词：

D O I：

10.1002/jhet.5570320438

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Pd(O)-Catalyzed allylations of 4(5)-nitroimidazole, 1, 2-methyl-4(5)-nitroimidazole, 2, 4(5)-bromoimidazole, 7, 4(5)-methoxyimidazole, 10, 5(6)-nitrobenzimidazole, 16a, 5(6)-methylbenzimidazole, 16b, benzotriazole, 19, and 5(6)-methylbenzotriazole, 22, were studied under several reaction conditions. Nitroimidazoles 1 and 2 were regioselectively allylated under thermodynamic control, leading to 1-allyl-4-nitro derivatives.

引用

页码：1325 / 1334

页数：10

共 54 条

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