SOLVATION NUMBER OF SODIUM ION

被引：7

作者：

AHMAD, N ^{[1
]}

DAY, MC ^{[1
]}

机构：

[1] LOUISIANA STATE UNIV,DEPT CHEM,BATON ROUGE,LA 70803

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1978年 / 40卷 / 07期

关键词：

D O I：

10.1016/0022-1902(78)80054-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new method for the determination of the inner sphere solvation number of the sodium ion is presented based on the distribution of donor between two liquid phases. The system sodium tetraethylaluminate (NaAlEt4-benzene (or cyclohexane)-donor forms two liquid phases with the salt in the lower phase and the distribution of donor between the two phases being strongly affected by solvation with the salt. A solvation number of six is obtained with tetrahydrofuran, pyridine, dimethoxyethane and dimethylsulfoxide. © 1978.

引用

页码：1383 / 1385

页数：3

共 21 条

[11]

LINDHEIMER A, 1972, J CHIM PHYS PHYSICOC, V69, P1454

[12] NMR STUDIES OF AQUEOUS ELECTROLYTE SOLUTIONS .I. HYDRATION NUMBER OF NACL DETERMINED FROM TEMPERATURE EFFECTS ON PROTON SHIFT [J].