ACETYLIDE ANIONS EXERT COMPLETE CONTROL OVER ALDOLIZATION DURING THE DIRECT CONVERSION OF SQUARATE ESTERS INTO POLYQUINANES

被引：27

作者：

MORWICK, T ^{[1
]}

DOYON, J ^{[1
]}

PAQUETTE, LA ^{[1
]}

机构：

[1] OHIO STATE UNIV,EVANS CHEM LABS,COLUMBUS,OH 43210

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 14期

关键词：

D O I：

10.1016/0040-4039(95)00279-L

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The sequential condensation of diisopropyl squarate with a vinyl anion and a lithium acetylide triggers a cascade of mechanistic events that eventuates in formation of highly functionalized unsaturated diquinanes.

引用

页码：2369 / 2372

页数：4

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