SOME CHEMICAL-TRANSFORMATIONS OF THE NEOCLERODANE DITERPENE TEUBOTRIN

被引：9

作者：

MALAKOV, PY

DELATORRE, MC

RODRIGUEZ, B

PAPANOV, GY

机构：

[1] CSIC,INST QUIM ORGAN,JUAN DE LA CIERVA 3,E-28006 MADRID,SPAIN

[2] PAISIJ HILENDARSKI UNIV PLOVDIV,DEPT ORGAN CHEM,BU-4000 PLOVDIV,BULGARIA

来源：

TETRAHEDRON | 1991年 / 47卷 / 48期

关键词：

NEOCLERODANE DERIVATIVES; ALLYLIC OXIDATIONS; FORMATION OF LACTONES FROM ALLYLIC CYCLIC ETHERS; TRANSLACTONIZATIONS; PARTIAL SYNTHESIS OF TEUSCORDINON;

D O I：

10.1016/S0040-4020(01)96062-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Starting from the natural neo-clerodane diterpenoid teubotrin (1) several neo-clerodane derivatives (3-7,9-11) have been obtained. The naturally occuring diterpenoid teuscordinon (12) has also been synthesized from teubotrin (1), showing thereby how some of these transformations can be useful for the synthesis of other natural neo-clerodane diterpenes. The latter are of interest due to their activity as insect antifeedants and other important biological properties.

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页码：10129 / 10136

页数：8

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