SYNTHESES AND STRUCTURES OF DECAMETHYLBIFERROCENE MONO-CATION AND DI-CATION TRIIODIDES

被引：27

作者：

DELVILLE, MH

ROBERT, F

GOUZERH, P

LINARES, J

BOUKHEDDADEN, K

VARRET, F

ASTRUC, D

机构：

[1] LAB CHIM ORGAN & ORGANOMET,CNRS,URA 35,351 COURS LIBERAT,F-33405 TALENCE,FRANCE

[2] UNIV PARIS 06,CHIM MET TRANSIT LAB,CNRS,URA 419,F-75252 PARIS 05,FRANCE

[3] UNIV PARIS 06,DEPT RECH PHYS,CNRS,URA 71,F-75252 PARIS 05,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 451卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83036-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mono- and di-cations of decamethylbiferrocene (1) have been obtained as triiodide salts by oxidation of decamethylbiferrocene with I2 in THF. The X-ray crystal structure Of [1](I3) at 295 K and the Mossbauer data show a localized mixed-valence system. The salt [1](I3)2 has a single Mossbauer quadrupole doublet at 4.5 K with Fe(III) parameters (IS-0.537 mm s-1 vs. Fe; QS=0.237 mm s-1) with small antiferromagnetic coupling (theta = - 5.58 K).

引用

页码：C10 / C12

页数：3

共 29 条

[1] ASPECTS OF AROMATIC IRON SANDWICHES - APPLICATION TO ORGANIC AND ORGANOMETALLIC SYNTHESIS [J].