THE USE OF 1,2-TRANS-CYCLOHEXANEDIOL AS AN EFFICIENT CHIRAL AUXILIARY FOR THE ASYMMETRIC CYCLOPROPANATION OF ALLYLIC ETHERS

被引：27

作者：

CHARETTE, AB

MARCOUX, JF

机构：

[1] Département de chimie, Université de Montréal, Montréal

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 45期

关键词：

D O I：

10.1016/S0040-4039(00)79275-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new and simple chiral auxiliary derived from optically pure 1,2-trans-cyclohexanediol was developed for the asymmetric Simmons-Smith cyclopropanation of substituted allylic alcohols. Excellent yields and diastereoselectivities were obtained with a variety of olefins.

引用

页码：7157 / 7160

页数：4

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