NOVEL ENANTIOSELECTIVE REACTION OF DIKETENE WITH ALDEHYDES PROMOTED BY CHIRAL SCHIFF BASE TITANIUM ALKOXIDE COMPLEX

被引：46

作者：

HAYASHI, M ^{[1
]}

INOUE, T ^{[1
]}

OGUNI, N ^{[1
]}

机构：

[1] YAMAGUCHI UNIV,FAC SCI,DEPT CHEM,YAMAGUCHI 753,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 03期

关键词：

D O I：

10.1039/c39940000341

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of a variety of aldehydes with diketene in the presence of chiral Schiff base-titanium alkoxide complexes proceeds with high enantioselectivity to afford the corresponding 5-hydroxy-3-oxoesters.

引用

页码：341 / 342

页数：2

共 20 条

[11] SYNTHESIS OF AN HMG-COA REDUCTASE INHIBITOR - A DIASTEREOSELECTIVE ALDOL APPROACH [J].

LYNCH, JE ;

VOLANTE, RP ;

WATTLEY, RV ;

SHINKAI, I .

TETRAHEDRON LETTERS, 1987, 28 (13) :1385-1388

[12]

Morrison J. D., 1984, ASYMMETRIC SYNTHESIS, V3

[13] ENANTIOSELECTIVE ADDITION OF ORGANOMETALLIC REAGENTS TO CARBONYL-COMPOUNDS - CHIRALITY TRANSFER, MULTIPLICATION, AND AMPLIFICATION [J].

NOYORI, R ;

KITAMURA, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1991, 30 (01) :49-69

[14]

NOYORI R, 1989, MOD SYN MET, V5, P115

[15] THE SYNTHESIS OF MEVINIC ACIDS [J].

ROSEN, T ;

HEATHCOCK, CH .

TETRAHEDRON, 1986, 42 (18) :4909-4951

[16] SYNTHESIS OF A CHIRAL SYNTHON FOR THE LACTONE PORTION OF COMPACTIN AND MEVINOLIN [J].

ROTH, BD ;

ROARK, WH .

TETRAHEDRON LETTERS, 1988, 29 (11) :1255-1258

[17]

SHAO L, 1991, TETRAHEDRON LETT, V52, P7699

[18] ASYMMETRIC HYDROGENATION OF 3,5-DIOXOESTERS CATALYZED BY RU-BINAP COMPLEX - A SHORT STEP ASYMMETRIC-SYNTHESIS OF 6-SUBSTITUTED 5,6-DIHYDRO-2-PYRONES [J].

SHAO, LM ;

KAWANO, H ;

SABURI, M ;

UCHIDA, Y .

TETRAHEDRON, 1993, 49 (10) :1997-2010

[19]

TAKANO S, 1989, SYNTHESIS-STUTTGART, P539

[20]

TOMIOKA K, 1990, SYNTHESIS-STUTTGART, P541

← 1 2 →