POLARIZED SINGLET-TRIPLET ABSORPTION SPECTRA OF NORMAL AND DEUTERATED ANTHRACENE CRYSTALS

被引：22

作者：

DUROCHER, G

WILLIAMS, DF

机构：

[1] Division of Pure Chemistry, National Research Council of Canada, Ottawa

[2] Chemistry Department, University of Montreal, Montreal, Que.

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 12期

关键词：

D O I：

10.1063/1.1671963

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The singlet-triplet absorption spectra of anthracene-f10 and anthracene-Jio crystals have been measured along the a and b crystal axes for temperatures between 350 and 4°K. The delayed fluorescence intensity was used to monitor the absorption. The Franck-Condon overlap factor was found to change with temperature, and the change is discussed in terms of variations in the C-C bond order. A vibrational analysis of the low temperature spectra is given.

引用

页码：5405 / &

共 47 条

[41] RADIATIONLESS TRANSITIONS IN POLYATOMIC MOLECULES .I. CALCULATION OF FRANCK-CONDON FACTORS [J].