THE ANGULAR TRIFLUOROMETHYL GROUP .2. SYNTHESIS OF (+)2,3,7,7A-TETRAHYDRO-7A-TRIFLUOROMETHYL-1H-INDENE-1,5-(6H)-DIONE

被引：13

作者：

BLAZEJEWSKI, JC

机构：

[1] CNRS - CERCOA, 94320 Thiais

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1990年 / 46卷 / 03期

关键词：

D O I：

10.1016/S0022-1139(00)82934-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Michael Condensation of 2-trifluoromethyl-cyclopentane-1,3-dione with methyl vinyl ketone, followed by amino-acid mediated cyclization of the resulting prochiral triketone, gives access to optically active (+) 2,3,7,7a - tetrahydro -7a- trifluoromethyl -1H- indene -1,5-(6H)-dione. © 1990.

引用

页码：515 / 519

页数：5

共 13 条

[11] TOTAL SYNTHESES OF OPTICALLY-ACTIVE 19-NORSTEROIDS - (+)-ESTR-4-ENE-3,17-DIONE AND (+)-13BETA-ETHYLGON-4-ENE-3,17-DIONE
MICHELI, RA
HAJOS, ZG
COHEN, N
PARRISH, DR
PORTLAND, LA
SCIAMANNA, W
SCOTT, MA
WEHRLI, PA
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (06) : 675 - 681
[12] FLUORINATING ANNELATION OF CARBONYL-COMPOUNDS BY 1-FLUOROVINYLMETHYL KETONE
MOLINES, H
WAKESELMAN, C
[J]. TETRAHEDRON, 1976, 32 (17) : 2099 - 2103
[13] UDER U, 1971, ANGEW CHEM INT EDIT, V10, P496

← 1 2 →