KINETICS OF REACTION BETWEEN SODIUM HYDROXIDE AND IODOPENTAMMINECOBALT(3) PERCHLORATE IN AQUEOUS SOLUTION

被引：6

作者：

DAVIES, MB

LALOR, GC

机构：

[1] Chemistry Department, University of the West Indies

来源：

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 07期

关键词：

D O I：

10.1016/0022-1902(69)90037-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Second-order rate constants for the reaction between iodopentamminecobalt(III) and hydroxide ions were measured spectrophotometrically at low ionic strengths in the temperature range 2·6-20°C. The variation of rate constants with ionic strength follows the predictions of the Brönsted-Bjerrum theory. At zero ionic strength the variation of the rate constant with respect to temperature is reproduced by the equation: k20(1.mole-1)= 4.19x1021 exp(-27.812±251) RT. © 1969.

引用

页码：2189 / &

共 7 条

[1] KINETICS OF REACTION BETWEEN SODIUM HYDROXIDE AND CHLOROPENTAMMINECOBAL(3) PERCHLORATE IN AQUEOUS SOLUTION [J].