2,4,6-TRIFLUOROPHENYL GOLD(I) AND GOLD(III) COMPLEXES

被引：15

作者：

LAGUNA, A

LAGUNA, M

JIMENEZ, J

FUMANAL, AJ

机构：

[1] Departamento de Química Inorgánica, Instituto de Ciencia de Materials de Aragón, Universidad de Zaragoza-C.S.I.C.

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 396卷 / 01期

关键词：

D O I：

10.1016/0022-328X(90)85199-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Displacement of tetrahydrothiophen (tht) from AuR(tht) (R = 2,4,6-C6F3H2) by anionic ligands gives [AuRX]-, which reacts with AgClO4 or AgR to give [AuR]4, [RAuSCNAuR]- or [AuAgR2]x. Neutral [AuR3L (L = PPh3, AsPh3, SbPh3, OPPh3, SPPh3, NCMe, NCPr, NCPh, NC(CHCH2), o-(NC)2C6H4 or py), (μ-4,4′-bipy)AuR3 or cis-AuR2Cl(py)], anionic {(NBu4)[AuR3Br] or (NBu4)[AuR4]} or cationic {trans-[AuR2(4,4′-bipy)]ClO4} gold(III) complexes are obtained by displacement of the ether ligand of AuR3(OEt2), AuR2Cl(OEt2) or [AuR2(OEt2)2] ClO4. © 1990.

引用

页码：121 / 128

页数：8