ORGANOIMIDO LIGANDS WITH REMOTE FUNCTIONALITY - A P-PYRIDYLIMIDO COMPLEX OF VANADIUM(V) AND ITS USE AS A METALLOLIGAND

被引:26
作者
HILL, PL
YAP, GPA
RHEINGOLD, AL
MAATTA, EA
机构
[1] KANSAS STATE UNIV AGR & APPL SCI, DEPT CHEM, MANHATTAN, KS 66506 USA
[2] UNIV DELAWARE, DEPT CHEM, NEWARK, DE 19716 USA
关键词
D O I
10.1039/c39950000737
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The exposed nitrogen atom of the p-pyridylimido ligand in the vanadium(v) species [(N3N)V=N-C5H4N] 1 {N3N = [(Me(3)SiNCH(2)CH(2))(3)N](3-)} provides a reactive site capable of complexing a second metal fragment, enabling the construction of new types of heterobimetallic complexes linked by a compact conjugated bridge.
引用
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页码:737 / 738
页数:2
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