STUDY OF REDUCED MO/AL2O3 METATHESIS CATALYSTS PREPARED VIA METAL-COMPLEXES

被引：7

作者：

KLIMOV, OV

ALEKSEEV, OS

STARTSEV, AN

机构：

[1] Federal Scientific Center, Boreskov Institute of Catalysis, Novosibirsk

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1995年 / 56卷 / 01期

关键词：

D O I：

10.1007/BF02066961

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Mo/Al2O3 catalysts for propene metathesis were prepared both via anchoring Mo complexes of various nuclearities and by conventional method of impregnation. The catalysts from metal complexes were found to be active in metathesis at ambient temperature after reduction with H-2 or CO at 400-500 degrees C. The average oxidation state of Mo in the activated catalysts was determined with regard to oxygen consumption needed for oxidation of the reduced Mo species to Mo6+.

引用

页码：143 / 150

页数：8