STRUCTURE OF THE COMPLEX DICYTOSINIUM TETRACHLOROCUPRATE

被引：17

作者：

OGAWA, K

NISHITANI, K

FUJIWARA, T

SHIROTAKE, S

TOMITA, KI

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS | 1979年 / 35卷 / APR期

关键词：

D O I：

10.1107/S0567740879005288

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystallographic structure of [C4H6N3O]2[CuCl4] is as follows: triclinic, P.hivin.1, a = 13.689, b = 9.537, c = 6.936 .ANG., .alpha. = 102.93, .beta. = 105.59, .gamma. = 112.24, Z = 2, Dm = 1.875 Mg m-3. The final R value is 0.082 for 2711 non-zero reflections observed on a diffractometer. There is no direct coordination between the metal atoms and cytosinium cations. The base pairing related by a center of symmetry is formed by 2 N.sbd.H.cntdot..cntdot..cntdot.O hydrogen bonds (2.85 .ANG.). The main intermolecular interactions consist of 5 kinds of N.sbd.H.cntdot..cntdot..cntdot.Cl hydrogen bonds.

引用

页码：965 / 967

页数：3

共 7 条

[1] CRYSTAL-STRUCTURE OF THIAMINE HYDROCHLORIDE COPPER(II) COMPLEX [J].

CAIRA, MR ;

FAZAKERLEY, GV ;

LINDER, PW ;

NASSIMBENI, LR .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1974, 30 (JUL15) :1660-1666

[2] STRUCTURE OF THE COMPLEX CYTOSINIUM HEMITETRACHLOROZINCATE-CYTOSINE [J].

FUJINAMI, F ;

OGAWA, K ;

ARAKAWA, Y ;

SHIROTAKE, S ;

FUJII, S ;

TOMITA, KI .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1979, 35 (APR) :968-970

[3]

HAMILTON WC, 1968, HYDROGEN BOND SOLIDS

[4] PLATINUM COMPOUND BINDING BY PURINE AND PYRIMIDINE-BASES .1. STRUCTURE OF [CYTOSINE.H+]2[PDCL24-] [J].

KINDBERG, BL ;

AMMA, EL .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1975, 31 (MAY15) :1492-1494

[5] CRYSTAL-STRUCTURE OF TRIETHYLAMMONIUM TETRACUPRICHLORIDE, [(C2H5)3NH]2CUCL4 [J].

LAMOTTEBRASSEUR, J ;

DUPONT, L ;

DIDEBERG, O .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1973, 29 (FEB15) :241-246

[6] LOCATION OF HYDROGEN ATOMS IN CERTAIN HETEROCYCLIC COMPOUNDS [J].

SINGH, C .

ACTA CRYSTALLOGRAPHICA, 1965, 19 :861-&

[7]

1974, INT TABLES XRAY CRYS, V4, P71

← 1 →