MOBILITY OF PLUTONIUM AND AMERICIUM THROUGH A SHALLOW AQUIFER IN A SEMIARID REGION

Treated liquid wastes containing traces of plutonium and americium are released into Mortandad Canyon, within the site of Los Alamos National Laboratory, NM. The wastes infiltrate a small aquifer within the canyon. Although laboratory studies have predicted that the movement of actinides in subsurface environments will be limited to less than a few meters, both plutonium and americium are detectable in monitoring wells as far as 3390 m downgradient from the discharge. Between the first and last monitoring wells (1.8 and 3.4 km from the discharge), plutonium concentrations decreased exponentially from 1400 to 0.55 mBq/L. Americium concentrations ranged between 94 and 1240 mBq/L, but did not appear to vary in a systematic way with distance. Investigation of the properties of the mobile actinides indicates that the plutonium and part of the americium are tightly or irreversibly associated with colloidal material between 25 and 450 nm in size. The colloidally bound actinides are removed only gradually from the groundwater. The fraction of the americium not associated with colloids exists in a low molecular weight form, (diameter, ≤2 nm) and appears to be a stable, anionic complex of unknown composition. The mobile forms of these actinides defeat the forces that normally act to retard their movement through groundwater systems. © 1990, American Chemical Society. All rights reserved.