RECENT ADVANCES IN SOLVATION MODELS FOR STATIONARY PHASE CHARACTERIZATION AND THE PREDICTION OF RETENTION IN GAS-CHROMATOGRAPHY

被引:115
作者
POOLE, CF
KOLLIE, TO
POOLE, SK
机构
[1] Department of Chemistry, Wayne State University, Detroit, 48202, MI
关键词
GAS-LIQUID CHROMATOGRAPHY; THERMODYNAMIC MODELS; SOLVENT SELECTIVITY; MULTIVARIATE ANALYSIS; STATIONARY PHASES;
D O I
10.1007/BF02268359
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Rapid progress has been made in the last few years in the development of solvation models for gas chromatography. These models are based on the free energy of transfer of a solute from the gas phase to solution consisting of the additive processes of cavity formation and solute-solvent interactions expressed as dispersion, orientation, induction and hydrogen-bond formation. The adaptation of these models to characterize solvent selectivity for a wide range of common stationary phases and to the prediction of retention is critically discussed. The need to use high quality retention data in the further elaboration of solvation models is also demonstrated.
引用
收藏
页码:281 / 302
页数:22
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  • [1] STUDIES ON AMPHIPROTIC COMPOUNDS .4. APPLICATION OF THE ALPHA-H-2 HYDROGEN-BONDING ACIDITY SCALE TO COMPLEXATION BETWEEN PYRIDINE N-OXIDE AND MONOMERIC HYDROGEN-BOND DONORS IN CYCLOHEXANE
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    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (07) : 2230 - 2232
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    GENTRIC, E
    SRAIDI, K
    LAURANSAN, J
    GUIHENEUF, G
    KAMLET, MJ
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  • [3] SOLVATION OF GASEOUS NON-ELECTROLYTES
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    ABRAHAM, MH
    WHITING, GS
    DOHERTY, RM
    SHUELY, WJ
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    DOHERTY, RM
    KAMLET, MJ
    HALL, TN
    TAFT, RW
    CARR, PW
    KOROS, WJ
    [J]. POLYMER, 1987, 28 (08) : 1363 - 1369
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