STERICALLY OVERLOADED SILICON-COMPOUNDS .6. TETRAKIS(TRI-TERT-BUTYLSILYL)-TETRAHEDRO-TETRASILANE (TBU3SI)4SI4 - 1ST MOLECULAR SILICON COMPOUND WITH A SI4 TETRAHEDRON

被引：124

作者：

WIBERG, N

FINGER, CMM

POLBORN, K

机构：

[1] Institut für Anorganische Chemie, Universität München, D-80333

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 07期

关键词：

D O I：

10.1002/anie.199310541

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Yellow-orange tetrakis(supersilyl)-tetrahedro-tetrasilane (1), the first derivative of tetrahedro-tetrasilane Si4H4, is stable to heat, light, water, and air, and is not reduced by sodium at temperatures below 70-degrees-C, but reacts with oxidants like tetracyanoethylene and bromine. Compound 1 was obtained in 57% yield from reaction (a).

引用

页码：1054 / 1056

页数：3

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