ALKANE OXIDATION BY AN IRON COMPLEX-HYDROGEN PEROXIDE SYSTEM IN ACETONITRILE - THE MODEL OF METHANEMONOOXYGENASE

被引：24

作者：

KHENKIN, AM

BELOVA, VS

SHILOV, AE

机构：

[1] USSR Academy of Sciences Institute of Chemical Physics, Chernogolovka

来源：

CATALYSIS LETTERS | 1990年 / 5卷 / 02期

关键词：

enzymes; hydrocarbons; hydrogen peroxide; iron complexes; Oxidation;

D O I：

10.1007/BF00763955

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidation of methane and other light alkanes in the system iron complex - hydrogen peroxide has been studied. The efficiency of this system of alkane oxidation depends on water concentration. The catalytic methanol formation from methane with respect to the binuclear iron complex has been observed. The role of iron-oxocomplexes in oxidation of alkanes by methanemonooxygenase and model systems is discussed. © 1990 J.C. Baltzer A.G. Scientific Publishing Company.

引用

页码：211 / 216

页数：6

共 13 条

[11]

Shilov A. E., 1984, ACTIVATION SATURATED

[12] MODELING THE DINUCLEAR SITES OF IRON BIOMOLECULES - SYNTHESIS AND PROPERTIES OF FE2O(OAC)2CL2(BIPY)2 AND ITS USE AS AN ALKANE ACTIVATION CATALYST [J].