MIXED QUINONE MONOKETALS VIA IODOBENZENE DIACETATE OXIDATION

被引:42
作者
FLECK, AE [1 ]
HOBART, JA [1 ]
MORROW, GW [1 ]
机构
[1] UNIV DAYTON,DEPT CHEM,300 COLL PK,DAYTON,OH 45469
关键词
D O I
10.1080/00397919208021090
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Oxidation of p-methoxyphenol, 4-methoxynaphthol and 4-acetamidophenol with iodobenzenediacetate in various alcohols as solvent afforded the corresponding mixed quinone or naphthoquinone monoketals in good yield. Oxidation of p-methoxyphenol in the presence of sorbyl alcohol led to in situ intramolecular Diels-Alder reactions proceeding by way of the corresponding mixed quinone monoketal.
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页码:179 / 187
页数:9
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