Rotational excitation in molecular collisions: Exact (two-state) results versus variational (decoupling) computations

被引：10

作者：

Levine, R. D.

Shapiro, M.

Muckerman, J. T.

Johnson, B. R.

机构：

[1] Hebrew Univ Jerusalem, Dept Phys Chem, IL-91904 Jerusalem, Israel

[2] Univ Wisconsin, Inst Theoret Chem, Madison, WI USA

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 2卷 / 08期

关键词：

D O I：

10.1016/0009-2614(63)80010-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Transition probabilities for rotational excitation are evaluated exactly and compared with the predictions of a variational computation based on a decoupling procedure. The non-monotonic dependence on the asymmetry parameter is studied.

引用

页码：545 / 548

页数：4

共 14 条

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Levine, R. D.
Johnson, B. R.
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[J]. CHEMICAL PHYSICS LETTERS, 1968, 1 (11) : 517 - 520
[7] ADIABATIC APPROXIMATION FOR NONREACTIVE SUBEXCITATION MOLECULAR COLLISIONS
LEVINE, RD
[J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (01) : 51 - &
[8] COMPUTATIONAL INVESTIGATION OF INTERNAL EXCITATION IN NONREACTIVE MOLECULAR COLLISIONS - RESONANCES IN ROTATIONAL EXCITATION
LEVINE, RD
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MUCKERMAN, JT
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[J]. JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (01) : 56 - +
[9] LEVINE RD, RENORMALIZED S MATRI
[10] LEVINE RD, IN PRESS ROLE CURVE

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