INFLUENCING THE AGGREGATION OF MANGANESE COMPLEXES BY DIFFERENT BASES - FORMATION OF [MN(O2CCF3)2(PY)4] AND [MN3(O2CCF3)6(BENZ)6]

被引：35

作者：

HUBNER, K ^{[1
]}

ROESKY, HW ^{[1
]}

NOLTEMEYER, M ^{[1
]}

BOHRA, R ^{[1
]}

机构：

[1] UNIV GOTTINGEN, INST ANORGAN CHEM, TAMMANNSTR 4, W-3400 GOTTINGEN, GERMANY

来源：

CHEMISCHE BERICHTE-RECUEIL | 1991年 / 124卷 / 03期

关键词：

MANGANESE COMPLEXES; AGGREGATION;

D O I：

10.1002/cber.19911240316

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Manganese powder reacts quantitatively with trifluoroacetic acid to yield Mn(O2CCF3)2 (1). The aggregation of 1 is directed by different N-containing bases. Pyridine (py) forms the mononuclear complex [Mn(O2CCF3)2(py)4] (2), while benzonitrile (benz) yields the trinuclear complex [Mn3(O2CCF3)6(benz)6] (3). The X-ray structures of 2 and 3 are described.

引用

页码：515 / 517

页数：3

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