A NEW METHOD FOR THE SYNTHESIS OF [3]-CUMULENES AND ENEYNECUMULENES RELATED TO NEOCARZINOSTATIN CHROMOPHORE

被引：26

作者：

SAITO, I

YAMAGUCHI, K

NAGATA, R

MURAHASHI, E

机构：

[1] Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Kyoto

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 51期

关键词：

D O I：

10.1016/S0040-4039(00)88518-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convenient method for the synthesis of [3]-cumulenes based on a Horner-Emmons type reaction of allenyldiphenylphosphine oxides with aldehydes or ketones has been described. A facile two-step synthesis of eneynecumulenes has been accomplished by this method.

引用

页码：7469 / 7472

页数：4