CHIRAL ORGANOMETALLIC NADH MIMICS - STEREOSELECTIVE REDUCTION OF ETHYL BENZOYLFORMATE UTILIZING THE HOMOCHIRAL AUXILIARY [(ETA-5-C5H5)FE(CO)(PPH3)] AT C-3 AND A CHIRAL BETA-HYDROXY-CARBOXAMIDE DERIVED FROM VALINOL AT C-5

被引：25

作者：

BURGESS, VA ^{[1
]}

DAVIES, SG ^{[1
]}

SKERLJ, RT ^{[1
]}

机构：

[1] DYSON PERRINS LAB,S PARKS RD,OXFORD OX1 3QY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1990年 / 24期

关键词：

D O I：

10.1039/c39900001759

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Homochiral complexes incorporating the chiral auxiliary [(eta5-C5H5)Fe(CO)(PPh3)] at C-3 and a chiral beta-hydroxycarboxamide, derived from valinol, at C-5 reduce ethyl benzoylformate to ethyl mandelate in greater than 97% enantiomeric excess.

引用

页码：1759 / 1762

页数：4

共 17 条

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