PHOTOCATALYTIC REDUCTION OF COORDINATED DINITROGEN TO AMMONIA - MONONUCLEAR VERSUS DINUCLEAR ETHYLENEDIAMINETETRAACETATO RUTHENIUM COMPLEXES

被引：9

作者：

RAO, NN

机构：

[1] Photocatalysis Group, Central Salt and Marine Chemicals Research Institute, Bhavnagar

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 93卷 / 01期

关键词：

DINUCLEAR COMPLEXES; MONONUCLEAR COMPLEXES; NITROGEN; PHOTOCATALYSIS; REDUCTION; RUTHENIUM;

D O I：

10.1016/0304-5102(94)00097-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Experiments were conducted aiming for the reduction of coordinated nitrogen in mononuclear end-on dinitrogen complex, [Ru(Hedta) N-2](-) and dinuclear bridged complex, [Ru(Hedta)]N-2(2)2- using the conduction band electrons of illuminated Pt/CdS (lambda(ex) = 505 nm). It has been found that the dinitrogen in mononuclear end-on complex is more easily reduced to ammonia.

引用

页码：23 / 27

页数：5

共 27 条

[1]

CONESA JC, 1989, STUD SURF SCI CATAL, V48, P307

[2] PREPARATION AND STRUCTURE OF ETHYLENEDIAMINETETRAACETATE COMPLEXES OF RUTHENIUM(II) WITH DINITROGEN, CARBON-MONOXIDE, AND OTHER PI-ACCEPTOR LIGANDS [J].