A NEW TITANIUM SILICA CATALYST FOR THE EPOXIDATION OF NONFUNCTIONALIZED ALKENES AND ALLYLIC ALCOHOLS

被引：45

作者：

FRAILE, JM

GARCIA, JI

MAYORAL, JA

DEMENORVAL, LC

RACHDI, F

机构：

[1] UNIV ZARAGOZA,CSIC,FAC CIENCIAS,INST CIENCIA MAT ARAGON,DEPT QUIM ORGAN & QUIM FI,E-50009 ZARAGOZA,SPAIN

[2] LAB CHIM ORGAN PHYS & CINET CHIM APLIQUEES,CNRS,URA 418,F-34053 MONTPELLIER 1,FRANCE

[3] CNRS,URA 233,DYNAM PHASES CONDENSEES GRP,F-34095 MONTPELLIER 5,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 05期

关键词：

D O I：

10.1039/c39950000539

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Silica treated with Ti(OPri)(4) is an efficient catalyst for the tert-butyl hydroperoxide epoxidation of nonfunctionalized alkenes and allylic alcohols at room temperature; the reactivity of the olefinic substrate depends on the structure, which allows the selective epoxidation of compounds containing different types of double bonds; H-1 and C-13 CP-MAS NMR shows the presence of isopropoxide groups in the catalyst.

引用

页码：539 / 540

页数：2

共 13 条

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