CONTROL OF AGGREGATION THROUGH ANION ENCAPSULATION IN CLUSTERS OF THE V/O/RPO(3)(2-) SYSTEM - SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURES OF THE TETRANUCLEAR CLUSTERS [NBU(4)(N)][(V4(V)O6F)(PHPO3)(4)] AND [NBU(4)(N)](2)[V(V)(3)(V)(VI)O6F(PHPO3)(4)]

被引：31

作者：

CHEN, Q ^{[1
]}

ZUBIETA, J ^{[1
]}

机构：

[1] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 23期

关键词：

D O I：

10.1039/c39940002663

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of [(NBu(4)(n))][V5O7(PhPO(3))(5)(OMe)(2)] with HBF4.Et(2)O in acetonitrile yields the tetranuclear vanadium(v) cluster [NBu(4)(n)][V4O6F(PhPO(3))(4)] 1 which upon reduction with organohydrazine yields the mixed-valence cluster [NBu(4)(n)](2)[(V3VO6F)-V-V-O-IV(PhPO(3))(4)] 2.

引用

页码：2663 / 2664

页数：2

共 16 条

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