STEREOSPECIFIC REACTIONS OF THE M(C6F5)2 (M=PD OR PT) SYNTHONS TOWARDS CIS-DITHIOLATO COMPLEXES

被引：22

作者：

USON, R

FORNIES, J

USON, MA

HERRERO, S

机构：

[1] Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza - C.S.I.C.

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 447卷 / 01期

关键词：

D O I：

10.1016/0022-328X(93)80283-H

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of the general formula cis-[M(SC6F5)2L2] (M = Ni, Pd, or Pt; L2 = dppm [bis(diphenylphosphino)methane], dppe [1,2-bis(diphenylphosphino)ethane], or 2PPh3) were synthesized by the reaction (1: 2) between the corresponding cis-[MCl2L2] and Tl(SC6F5). When treated with cis-[M(C6F5)2(THF)2] (M = Pd or Pt; THF = OC4H8) they yield geminal homo- or hetero-binuclear compounds, which were characterized by IR, NMR and mass spectroscopy.

引用

页码：137 / 144

页数：8

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