ORGANOSILICON RADICAL-INDUCED CYCLIZATION REACTIONS

被引：20

作者：

KRAUS, GA

LIRAS, S

机构：

[1] Department of Chemistry, Iowa State University, Ames

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 37期

关键词：

D O I：

10.1016/S0040-4039(00)98046-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first examples of selective additions of organosilicon radicals are reported. Trichlorosilyl radicals preferentially attack the carbonyl oxygen atom, while triethylsilyl radicals preferentially attack alkenes. Carbon-carbon bond formation to produce both monocyclic and bridged bicyclic systems is possible. © 1990.

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页码：5265 / 5268

页数：4

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