A NEW KINETIC PATTERN FOR THE SUBSTITUTION-REACTIONS OF INORGANIC COMPLEXES - STUDIES ON [FE2S2CL4](2-)

被引：15

作者：

HENDERSON, RA

OGLIEVE, KE

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 17期

关键词：

D O I：

10.1039/c39940001961

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Kinetic studies on the substitution reactions of [Fe2S2Cl3(NCMe)](-) with the nucleophiles L = Br- or RS(-) (R = Et or But) to form [Fe2S2Cl3](2-) show that the rate of the reaction is inhibited by increasing the concentration of the nucleophile; this is a consequence of L binding to the iron atom not undergoing substitution.

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页码：1961 / 1962

页数：2

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