SYNTHESIS AND STRUCTURE OF DIFLUORO-BIS-[2,4,6-TRIS(FLUOROMETHYL)PHENYL]SILANE

被引：14

作者：

BUIJINK, JK ^{[1
]}

NOLTEMEYER, M ^{[1
]}

EDELMANN, FT ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 61卷 / 1-2期

关键词：

D O I：

10.1016/S0022-1139(00)80416-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

2,4,6-Tris(trifluoromethyl)phenyl-lithium (= R(F)Li) reacts with SiCl4 in a 2:1 molar ratio to give (R(F))2SiF2 (1) exclusively. The formation of 1 is a result of Cl/F exchange between an intermediate (R(F))2SiCl2 and the CF3 groups of the ligand. The structure of 1 has been determined by X-ray crystallography. The preparation of (R(F))2SbCl (2) is also described.

引用

页码：51 / 56

页数：6

共 8 条

[1] CAMBRIDGE CRYSTALLOGRAPHIC DATA CENTER - COMPUTER-BASED SEARCH, RETRIEVAL, ANALYSIS AND DISPLAY OF INFORMATION
ALLEN, FH
BELLARD, S
BRICE, MD
CARTWRIGHT, BA
DOUBLEDAY, A
HIGGS, H
HUMMELINK, T
HUMMELINKPETERS, BG
KENNARD, O
MOTHERWELL, WDS
RODGERS, JR
WATSON, DG
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (OCT): : 2331 - 2339
[2] SYNTHESIS, STRUCTURE, AND REACTIVITY OF THE 1ST STABLE DIARYLLEAD(II) COMPOUND
BROOKER, S
BUIJINK, JK
EDELMANN, FT
[J]. ORGANOMETALLICS, 1991, 10 (01) : 25 - 26
[3] POLYFLUOROARYL ORGANOMETALLIC COMPOUNDS .17. 2,4,6-TRIS(TRIFLUOROMETHYL)PHENYLLITHIUM, A STERICALLY CROWDED SYSTEM
CARR, GE
CHAMBERS, RD
HOLMES, TF
PARKER, DG
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 325 (1-2) : 13 - 23
[4] Edelmann F.T., 1992, COMMENTS INORG CHEM, V12, P259
[5] GRUTZMACHER H, 1991, ORGANOMETALLICS, V10, P23
[6] SYNTHESIS OF TETRAKIS(2,6-DIISOPROPYLPHENYL)DIGERMENE AND ITS REDUCTIVE CLEAVAGE TO THE CORRESPONDING DIGERMENYLLITHIUM-(DME) COMPLEX
PARK, J
BATCHELLER, SA
MASAMUNE, S
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 367 (1-2) : 39 - 45
[7] THE 2,4,6-TRIS(TRIFLUOROMETHYL)PHENYL SUBSTITUENT - EXAMPLES FOR ELECTRONICALLY AND STERICALLY STABILIZED LOW-COORDINATED MAIN-GROUP ELEMENTS
SCHOLZ, M
ROESKY, HW
STALKE, D
KELLER, K
EDELMANN, FT
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 366 (1-2) : 73 - 85
[8] STERICALLY CROWDED ARYL BISMUTH COMPOUNDS - SYNTHESIS AND CHARACTERIZATION OF BIS(2,4,6-TRIS(TRIFLUOROMETHYL)PHENYL) BISMUTH CHLORIDE AND TRIS(2,4,6-TRIS(TRIFLUOROMETHYL)PHENYL) BISMUTH
WHITMIRE, KH
LABAHN, D
ROESKY, HW
NOLTEMEYER, M
SHELDRICK, GM
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 402 (01) : 55 - 66

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