CALCULATION OF MADELUNG ENERGY OF IONIC THIOUREA COMPLEXES

被引：16

作者：

BOEYENS, JCA

GAFNER, G

机构：

[1] Chemical Physics Group, National Chemical and Physical Research Laboratories, CSIR, Pretoria

来源：

JOURNAL OF CHEMICAL PHYSICS | 1968年 / 49卷 / 05期

关键词：

D O I：

10.1063/1.1670419

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The Madelung interactions between the ions and dipoles in a typical complex of thiourea with an ionic salt have been calculated by numerical methods. The calculations show that the cohesion in the complexes is almost exclusively due to electrostatic interactions and that complexing only occurs, for energetic reasons, with ionic salts which have lattice energies of less than ~160 kcal/mole.

引用

页码：2435 / &

共 14 条

[11] A DETAILED REFINEMENT OF THE CRYSTAL AND MOLECULAR STRUCTURE OF THIOUREA
KUNCHUR, NR
TRUTER, MR
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1958, (JUL): : 2551 - 2557
[12] KOMPLEXVERBINDUNGEN VON THALLIUM .2. KOMPLEXE VON THALLIUM(1) MIT THIOHARNSTOFF
PFREPPER, G
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1966, 347 (3-4): : 160 - &
[13] INFRARED ABSORPTION SPECTRA OF UREA, THIOUREA, AND SOME THIOUREA-ALKALI HALIDE COMPLEXES
STEWART, JE
[J]. JOURNAL OF CHEMICAL PHYSICS, 1957, 26 (02) : 248 - 254
[14] VERHOEF LHW, TO BE PUBLISHED

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