KINETIC RESOLUTION OF ALPHA-SUBSTITUTED KETONES BY WITTIG REACTION USING A CHIRAL TRICYCLIC PHOSPHONATE

被引：35

作者：

NARASAKA, K ^{[1
]}

HIDAI, E ^{[1
]}

HAYASHI, Y ^{[1
]}

GRAS, JL ^{[1
]}

机构：

[1] FAC SCI & TECH ST JEROME,CNRS,URA 1411,F-13397 MARSEILLE 13,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 02期

关键词：

D O I：

10.1039/c39930000102

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Wittig reactions of alpha-substituted ketones using a chiral phosphonate derived from mannitol afford chiral olefins by kinetic resolution.

引用

页码：102 / 104

页数：3

共 11 条

[1] ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETIC ACID, A VERSATILE REAGENT FOR DETERMINATION OF ENANTIOMERIC COMPOSITION OF ALCOHOLS AND AMINES
DALE, JA
DULL, DL
MOSHER, HS
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (09) : 2543 - &
[2] STEREOSELECTIVE ALKYLATIONS OF CHIRAL, PHOSPHORUS-STABILIZED BENZYLIC CARBANIONS
DENMARK, SE
DOROW, RL
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (24) : 5926 - 5928
[3] TRANSACETALATION OF TRIOLS FROM DIMETHOXYMETHANE - SELECTIVITY AND SYNTHETIC APPLICATIONS
GRAS, JL
NOUGUIER, R
MCHICH, M
[J]. TETRAHEDRON LETTERS, 1987, 28 (52) : 6601 - 6604
[4] GRAS JL, 1992, SYNTHETIC COMMUN, V22, P405
[5] DESIGN AND REACTIVITY OF TOPOLOGICALLY UNIQUE, CHIRAL PHOSPHONAMIDES - REMARKABLE DIASTEREOFACIAL SELECTIVITY IN ASYMMETRIC OLEFINATION AND ALKYLATION
HANESSIAN, S
DELORME, D
BEAUDOIN, S
LEBLANC, Y
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (19) : 5754 - 5756
[6] OPTICALLY-ACTIVE ALLYLSILANES .1. PREPARATION BY PALLADIUM-CATALYZED ASYMMETRIC GRIGNARD CROSS-COUPLING AND ANTI STEREOCHEMISTRY IN ELECTROPHILIC SUBSTITUTION-REACTIONS
HAYASHI, T
KONISHI, M
ITO, H
KUMADA, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (18) : 4962 - 4963
[7] OPTICALLY-ACTIVE ALLYLSILANES .10. ASYMMETRIC-SYNTHESIS CATALYZED BY CHIRAL FERROCENYLPHOSPHINE TRANSITION-METAL COMPLEXES .3. PREPARATION OF OPTICALLY-ACTIVE ALLYLSILANES BY PALLADIUM-CATALYZED ASYMMETRIC GRIGNARD CROSS-COUPLING
HAYASHI, T
KONISHI, M
OKAMOTO, Y
KABETA, K
KUMADA, M
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (20) : 3772 - 3781
[8] ENANTIOSELECTIVE ALKYLATION OF KETONES VIA CHIRAL, NON-RACEMIC LITHIOENAMINES - AN ASYMMETRIC-SYNTHESIS OF ALPHA-ALKYL AND ALPHA, ALPHA'-DIALKYL CYCLIC-KETONES
MEYERS, AI
WILLIAMS, DR
ERICKSON, GW
WHITE, S
DRUELINGER, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (11) : 3081 - 3087
[9] STEREOSELECTIVE HYDROGENATION VIA DYNAMIC KINETIC RESOLUTION
NOYORI, R
IKEDA, T
OHKUMA, T
WIDHALM, M
KITAMURA, M
TAKAYA, H
AKUTAGAWA, S
SAYO, N
SAITO, T
TAKETOMI, T
KUMOBAYASHI, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (25) : 9134 - 9135
[10] CONFORMATIONAL-ANALYSIS OF THE AMINO TERMINI (5 RESIDUES) OF HUMAN GLYCOPHORIN-AM AND GLYCOPHORIN-A(N) - DIFFERENTIATION OF THE STRUCTURAL FEATURES OF THE TN AND T ANTIGENIC DETERMINANTS IN RELATION TO THEIR SPECIFICITY
PEPE, G
SIRI, D
ODDON, Y
PAVIA, AA
REBOUL, JP
[J]. CARBOHYDRATE RESEARCH, 1991, 209 : 67 - 81

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