CARBONIUM ION FORMATION IN SOLVOLYSIS OF PHOSPHATE TRIESTERS

被引：20

作者：

COX, JR

NEWTON, MG

机构：

[1] School of Chemistry, Institute of Technology, Atlanta

[2] Department of Chemistry, University of Houston, Houston

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 09期

关键词：

D O I：

10.1021/jo01261a025

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The mechanisms of solvolysis of some triesters of phosphoric acid which might form carbonium ions have been investigated. Such a pathway is shown to be predominant in the solvolysis of tri-t-butyl and triisopropyl phosphates, but to be negligible in the case of triallyl phosphate. The solvolytic behavior of some five-membered cyclic tertiary alkyl esters is briefly discussed. © 1969, American Chemical Society. All rights reserved.

引用

页码：2600 / &

共 18 条

[1] ANBAR M, 1959, INT J APPL RADIAT IS, V4, P233
[2] ARBUZOV AE, 1949, IAN SSSR KH, P473
[3] REACTIONS OF ORGANIC PHOSPHATES .5. HYDROLYSIS OF TRIPHENYL AND TRIMETHYL PHOSPHATES
BARNARD, PW
VERNON, CA
LLEWELLYN, DR
WELCH, VA
BUNTON, CA
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1961, (JUL): : 2670 - &
[4] THE MECHANISM OF THE HYDROLYSIS OF TRIMETHYL ORTHOPHOSPHATE
BLUMENTHAL, E
HERBERT, JBM
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1945, 41 (10): : 611 - 617
[5] HYDROLYSES OF ALPHA-D-RIBOSE AND ALPHA-D-GLUCOSE 1-PHOSPHATE
BUNTON, CA
HUMERES, E
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (03) : 572 - &
[6] HYDROLYSIS OF METHYL ETHYLENE PHOSPHATE - STERIC HINDRANCE IN GENERAL BASE CATALYSIS
COVITZ, F
WESTHEIMER, FH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1963, 85 (12) : 1773 - &
[7] THE OXIDATION OF TRISUBSTITUTED PHOSPHITES BY DINITROGEN TETROXIDE
COX, JR
WESTHEIMER, FH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (20) : 5441 - 5443
[8] HYDROLYSIS AND EXCHANGE IN ESTERS OF PHOSPHORIC ACID
HAAKE, PC
WESTHEIMER, FH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (05) : 1102 - &
[9] Kosolapoff G. M., 1950, ORGANOPHOSPHORUS COM
[10] KUGAL L, 1967, J ORG CHEM, V32, P642

← 1 2 →