SUBADHESIVE HYDRATION OF ALUMINUM ADHERENDS AND ITS DETECTION BY ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY

被引：23

作者：

DAVIS, GD ^{[1
]}

WHISNANT, PL ^{[1
]}

VENABLES, JD ^{[1
]}

机构：

[1] VENABLES & ASSOCIATES,BALTIMORE,MD 21204

来源：

JOURNAL OF ADHESION SCIENCE AND TECHNOLOGY | 1995年 / 9卷 / 04期

关键词：

ADHESIVE BOND; ALUMINUM ADHEREND; BOND DURABILITY; HYDRATION; MOISTURE; INTERFACE; ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY; EIS; XPS;

D O I：

10.1163/156856195X00374

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Hydration of an aluminum oxide surface under an adhesive film was shown to occur when the specimen was immersed for extended periods in hot water. The absence of a crack and lack of access of the water to the specimen edges forced the moisture to reach the interface by migrating through the adhesive. The increased volume of the hydration product forced it to erupt through the adhesive. This subadhesive hydration is conclusive proof that hydration can proceed in advance of a crack to promote its propagation. Electrochemical impedance spectroscopy (EIS) measurements on the specimen during exposure readily detected both the ingress of moisture through the adhesive and the hydration of the substrate.

引用

页码：433 / 442

页数：10

共 31 条

[1]

Ahearn J.S., 1983, ADHESION ASPECTS POL, P281

[2] ADVANCES IN CHARGE NEUTRALIZATION FOR XPS MEASUREMENTS OF NONCONDUCTING MATERIALS [J].

BARTH, G ;

LINDER, R ;

BRYSON, C .

SURFACE AND INTERFACE ANALYSIS, 1988, 11 (6-7) :307-311

[3]

Brewis DM, 1980, INT J ADHES ADHES, V1, P35, DOI [DOI 10.1016/0143-7496(80)90032-9, 10.1016/0143-7496(80)90032-9]

[4]

Brockmann W., 1986, INT J ADHES ADHES, V6, P115, DOI [10.1016/0143-7496(86)90016-3, DOI 10.1016/0143-7496(86)90016-3]

[5]

CLEARFIELD HM, 1990, ENG MATERIALS HDB, V3, P259

[6]

COMPTON JS, 1989, J MATER SCI, V24, P1575

[7]

Comyn J., 1983, DURABILITY STRUCTURA, P85, DOI DOI 10.1002/(SICI)1099-0488(19971130)35:16<2659::AIDPOLB9>3.0.CO

[8]

2-K

[9]

Davis G.D., 1994, HDB ADHESIVE TECHNOL, P113

[10] APPLICATION OF SURFACE BEHAVIOR DIAGRAMS TO THE STUDY OF HYDRATION OF PHOSPHORIC-ACID ANODIZED ALUMINUM [J].

DAVIS, GD ;

SUN, TS ;

AHEARN, JS ;

VENABLES, JD .

JOURNAL OF MATERIALS SCIENCE, 1982, 17 (06) :1807-1818

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