ALPHA,BETA-FUNCTIONALIZATION OF ENONES VIA PENTACOVALENT OXAPHOSPHOLENES

被引：28

作者：

MCCLURE, CK

GROTE, CW

机构：

[1] University of Delaware, Department of Chemistry and Biochemistry Newark

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 39期

关键词：

D O I：

10.1016/S0040-4039(00)92373-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2,2,2-Triethoxy-1,2-lambda-5-oxaphospholene, 1, reacts under mild, neutral conditions with bromine, dialkyl azodicarboxylates, and oxaziridines to produce beta-heteroatom substituted gamma-ketophosphonates and beta-acyl vinyl phosphonate in high yields.

引用

页码：5313 / 5316

页数：4