The electromigration reliability of copper interconnect has been studied under dc, pulse-dc, and bipolar current stressing conditions. Electroless plating was used to selectively deposit Cu in oxide trenches by using Pd silicide as a catalytic layer at the bottom of the trenches to initiate copper deposition. The dc and pulse-dc lifetimes of Cu are found to be about two orders of magnitude longer than that of Al-2%Si at 275-degrees-C, and about four orders of magnitude longer than that of Al-2%Si when extrapolated to room temperature. On the other hand, Cu ac lifetimes are found to be comparable to the ac lifetimes of Al-2%Si. The pulse-dc lifetime of copper interconnects follows the similar frequency and duty factor dependence as aluminum and the prediction of the vacancy relaxation model.