THE CHEMISTRY OF BIS-SPIROACETALS - SYNTHESIS OF THE NOVEL 1,7,9-TRIOXADISPIRO[5.1.5.3]HEXADECANE RING-SYSTEM

被引：11

作者：

BRIMBLE, MA

RUSH, CJ

WILLIAMS, GM

BAKER, EN

机构：

[1] Department of Chemistry and Biochemistry, Massey University, Palmerston North, Private Bag

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 02期

关键词：

D O I：

10.1039/p19900000414

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of the novel bis-spiroacetal (1) via the addition of an α-sulphonyl carbanion to δ-valerolactone followed by an acid catalysed cyclization is described. The stereochemistry was determined by X-ray crystallography and 1H NMR spectroscopy.

引用

页码：414 / 416

页数：3