THERMODYNAMIC ASPECTS OF METASTABLE-PHASE FORMATION

被引:20
作者
BATTEZZATI, L
机构
[1] Dipartimento di Chimica Inorganica, Chimica Fisica e Chimica dei Materiali, Università di Torino, Torino, 10125
来源
PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES | 1990年 / 61卷 / 04期
关键词
D O I
10.1080/13642819008219290
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The behaviour of thermodynamic properties in metallic liquid glass-forming systems is reviewed. It is shown that they are compatible with the hypothesis of progressive ordering on cooling. Trends for the ideal glass-transition temperature are calculated as a function of composition for different types of phase diagram. The occurrence of amorphization by solid-state reaction is described on the basis of favourable thermodynamic conditions. Evidence for high-pressure amorphization is collected and different reaction mechanisms are discussed. Thermodynamic quantities for quasicrystalline phases are estimated and compared with those for glassy and equilibrium phases. © 1990 Taylor & Francis Ltd.
引用
收藏
页码:511 / 524
页数:14
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