SYNTHESIS AND OXIDATIVE ACTIVATION OF AN OXABICYCLO[7.2.1] ENEDIYNE

被引：33

作者：

BRANDSTETTER, T ^{[1
]}

MAIER, ME ^{[1
]}

机构：

[1] UNIV KONSTANZ,FAK CHEM,D-78434 CONSTANCE,GERMANY

来源：

TETRAHEDRON | 1994年 / 50卷 / 05期

关键词：

D O I：

10.1016/S0040-4020(01)80628-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxabicyclo[7.2.1] enediyne 23 which contains an ortho-methoxybenzyl group at the anomeric position was synthesized from methyl-2,3-anhydro-alpha-D-lyxofuranoside (7). Treatment of this stable bicyclic enediyne with ceric ammonium nitrate at room temperature in CH3CN/H2O gave the aromatized monocyclic compound 25.

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页码：1435 / 1448

页数：14

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