CHEMOSELECTIVE OXIDATIONS IN WATER OF FUNCTIONAL-GROUPS

被引：16

作者：

FRINGUELLI, F ^{[1
]}

PELLEGRINO, R ^{[1
]}

PIERMATTI, O ^{[1
]}

PIZZO, F ^{[1
]}

机构：

[1] UNIV PERUGIA,DIPARTIMENTO CHIM,I-06100 PERUGIA,ITALY

来源：

SYNTHETIC COMMUNICATIONS | 1994年 / 24卷 / 18期

关键词：

D O I：

10.1080/00397919408010580

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The organic functional groups, formyl, cyano, hydroxymethyl and methylsulfenyl, are oxidized with high yields in water only by using TBHP and controlling the pH of the reaction medium. In the presence of (CTA)(2)SO4, the oxidation of the easily oxidizable sulfide group is prevented and a highly chemoselective process is obtained. The role of the surfactant is discussed.

引用

页码：2665 / 2673

页数：9

共 16 条

[1] BUNHOI, 1946, B SOC CHIM FR, P139
[2] ION BINDING AND REACTIVITY AT CHARGED AQUEOUS INTERFACES
BUNTON, CA
NOME, F
QUINA, FH
ROMSTED, LS
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1991, 24 (12) : 357 - 364
[3] REACTIONS IN MICELLES OF CETYLTRIMETHYLAMMONIUM HYDROXIDE - TEST OF THE PSEUDOPHASE MODEL FOR KINETICS
BUNTON, CA
GAN, LH
MOFFATT, JR
ROMSTED, LS
SAVELLI, G
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1981, 85 (26) : 4118 - 4125
[4] BUNTON CA, 1986, ADV PHYS ORG CHEM, V22, P214
[5] FACILE AND SELECTIVE OXIDATION OF SULFIDES TO SULFOXIDES BY T-BUTYL HYDROPEROXIDE IN AQUEOUS-MEDIUM
FRINGUELLI, F
PELLEGRINO, R
PIZZO, F
[J]. SYNTHETIC COMMUNICATIONS, 1993, 23 (22) : 3157 - 3163
[6] REGIOSELECTIVE EPOXIDATION OF ALLYLIC ALCOHOLS WITH MONOPEROXYPHTHALIC ACID IN WATER
FRINGUELLI, F
GERMANI, R
PIZZO, F
SANTINELLI, F
SAVELLI, G
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (04) : 1198 - 1202
[7] FRINGUELLI F, 1992, SYNLETT, P475
[8] FRINGUELLI F, 1988, TETRAHEDRON LETT, V30, P1427
[9] CHEMOTHERAPEUTIC AGENTS OF THE SULPHONE TYPE .2. SULPHONES RELATED TO BENZAMIDINE AND BENZYLAMINE
FULLER, AT
TONKIN, IM
WALKER, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1945, (SEP-): : 633 - 640
[10] THE OXIDATION OF ORGANIC SULFIDES BY MORTIERELLA-ISABELLINA .2. EFFECTS OF SUBSTITUENTS ON THE STEREOCHEMISTRY OF SULFOXIDE FORMATION
HOLLAND, HL
POPPERL, H
NINNISS, RW
CHENCHAIAH, PC
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1985, 63 (05): : 1118 - 1120

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