[MN(C18H16N2O)(3)](CLO4)(2) - A POLYMERIC 34-MEMBERED AND 68-MEMBERED METALLACYCLIC NETWORK FORMING A NOVEL WOVEN POLYCATENATED STRUCTURE

被引：139

作者：

GOODGAME, DML

MENZER, S

SMITH, AM

WILLIAMS, DJ

机构：

[1] Chemistry Department, Imperical College of Science, London

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 05期

关键词：

CATENANES; COMPLEXES WITH OXYGEN LIGANDS; MANGANESE COMPOUNDS; METALLACYCLES; POLYMERS;

D O I：

10.1002/anie.199505741

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two interpenetrating networks of 34‐ and 68‐membered manganese‐containing macrocycles with the manganese atoms in octahedral environments (see picture) are present in the polycatenane structure of the title compound. This arrangement is stabilized by face‐to‐face and edgo‐to‐face π–π interactions. The mechanism of formation of this complex structure is as yet unclear. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：574 / 575

页数：2

共 13 条

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