ASYMMETRIC OXIDATION OF SULFIDES USING (SALEN)MANGANESE(III) COMPLEX AS A CATALYST

被引：68

作者：

NODA, K ^{[1
]}

HOSOYA, N ^{[1
]}

YANAI, K ^{[1
]}

IRIE, R ^{[1
]}

KATSUKI, T ^{[1
]}

机构：

[1] KYUSHU UNIV 33,FAC SCI,DEPT CHEM,HIGASHI KU,FUKUOKA 812,JAPAN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 12期

关键词：

D O I：

10.1016/S0040-4039(00)73187-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric oxidation of sulfides was examined by using (salen) manganese(III) complexes as catalysts and (8S,8'S,1''S,2''S)complex (3b) was found to show high asymmetric induction up to 90% ee. To be interested, however, (8R,8'R,1''S,2''S)complex (1a) that showed excellent asymmetric induction in the epoxidation of simple olefins was a poor catalyst for the oxidation of sulfides.

引用

页码：1887 / 1890

页数：4

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