HEXAARM STAR-SHAPED POLYSTYRENES BY CORE-FIRST METHOD

被引：30

作者：

CLOUTET, E ^{[1
]}

FILLAUT, JL ^{[1
]}

GNANOU, Y ^{[1
]}

ASTRUC, D ^{[1
]}

机构：

[1] UNIV BORDEAUX 1,CHIM POLYMERES ORGAN LAB,CNRS,URA 1192,F-33405 TALENCE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 21期

关键词：

D O I：

10.1039/c39940002433

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hexafunctional initiator C-6[(CH2)(2)p-C6H4CH(Cl)Me](6) is synthesized by Fe(eta-C5H5)(+) induced hexabenzylation of C(6)Me(6) followed by regiospecific acetylation, NaBH4 reduction and chlorination, and allows the living Cationic polymerization of styrene which yields hexaarm star-shaped polymers.

引用

页码：2433 / 2434

页数：2

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